Does 202, 201 & 304 Stainless Steel Rust?

Stainless Steel Things You Should Know

What’s Stainless Steel

What’s Stainless Steel

Stainless Steel Definition

Stainless steel is a type of steel that contains less than 2% carbon (C) and more than 2% iron.

In the process of making stainless steel, alloying elements such as chromium (Cr), nickel (Ni), manganese (Mn), silicon (Si), titanium (Ti), and molybdenum (Mo) are added to improve its performance and make it resistant to corrosion, or rust-free. This is what gives the steel its name: “stainless.”

Why Stainless Steel Has Different Grades?

The process of making stainless steel involves adding different types and amounts of alloy elements to produce various levels of performance.

To distinguish between these different levels, stainless steel is categorized into different grades.

The table below lists the common alloy elements used in decorative stainless steel and is provided for reference purposes only.

Stainless Steel Chemical Composition Chart (percentage %)

Steel GradesCSiMnPSCrNi
304≤0.08≤1.00≤2.00≤0.045≤0.0318-208-10
301≤0.15≤1.00≤2.00≤0.045≤0.0316-186-8
202≤0.15≤1.007.5-10≤0.05≤0.0317-194-6
201≤0.15≤1.005.5-7.5≤0.05≤0.0316-183.5-5.5

What Kind Of Stainless Steel Is Not Easy To Rust?

Stainless Steel Rust

Top 3 Factors Affecting Stainless Steel Rust:

Alloy Element Content

Generally, if the chromium content is 10.5%, the stainless steel is less likely to rust.

The higher the chromium-nickel content, the greater the resistance to corrosion.

For example, 304 stainless steel with a nickel content of 8-10% and a chromium content of 18-20% will typically not rust.

The manufacturing process of stainless steel can impact its resistance to corrosion.

Large stainless steel factories with advanced smelting technology, equipment, and techniques have better control over alloying elements, impurity removal, and billet cooling temperatures, resulting in more stable and reliable product quality. As a result, the stainless steel produced by these factories is less likely to rust.

In contrast, small steel plants with poor equipment and technology often have difficulty removing impurities during the smelting process, causing their stainless steel to be more prone to rusting.

External Environment

Stainless steel in a dry, well-ventilated environment is less likely to rust.

However, in high humidity, continuous rainy conditions, or environments with high acidity or alkalinity, stainless steel is more susceptible to rusting.

Even 304 grade stainless steel can rust if the surrounding environment is poor enough.

Is Non-Magnetic Stainless Steel Better? Does Magnetic Stainless Steel Not Equal 304 Grade?

Stainless Steel With Magnetic

Many customers go to the market with a small magnet in their pocket to test if the stainless steel is magnetic, believing that non-magnetic stainless steel is rust-free.

However, this is a common misunderstanding. The magnetic property of stainless steel is determined by its structure, not its rust resistance.

Different solidification temperatures during the manufacturing process result in different structures of stainless steel, such as ferrite, austenite, and martensitic. Ferrite and martensitic stainless steel are magnetic, while austenitic stainless steel has good mechanical properties and weldability but is not as corrosion-resistant as ferrite stainless steel.

The market also circulates low-nickel, high-manganese content stainless steel in the 200 and 300 series, which are non-magnetic but have lower performance compared to 304 stainless steel with a high nickel content.

Additionally, 304 stainless steel may exhibit slight magnetic properties after undergoing drawing, annealing, polishing, and casting processes.

Therefore, using magnetic properties to judge the quality of stainless steel is not a scientific method and can lead to misunderstandings.

Why Stainless Steel Also Rust?

Many customers go to the market with a small magnet in their pocket to determine if the stainless steel is magnetic, assuming that non-magnetic stainless steel is rust-free.

However, this is a false understanding. The magnetic property of stainless steel is determined by its structure, not its resistance to rust.

When customers see brown rust spots on the surface of stainless steel, they are often surprised, thinking that “stainless steel does not rust, if it does, then the steel quality must have a problem.”

In reality, this is a one-sided and misinformed view of stainless steel.

Stainless steel can still rust under certain conditions. It has the ability to resist atmospheric oxidation, but its resistance to corrosion in acid, alkali, and salt environments can change based on its chemical composition, state of interaction, conditions of use, and type of environmental media.

For example, 304 stainless steel has excellent anti-corrosion properties in a dry, clean atmosphere, but if it is moved to a coastal area, it will quickly rust in the salt-rich sea fog.

Therefore, not all types of stainless steel can resist corrosion and rust at all times.

Stainless steel forms a very thin, fine, and stable layer of chromium oxide on its surface, which prevents oxygen from infiltrating and oxidizing, and resists corrosion. But if this protective film is continuously damaged, air, liquid, and oxygen atoms will continuously infiltrate and separate metallic iron atoms, causing the surface to rust continuously.

There are many forms of damage to the protective film on stainless steel surfaces, including:

  • Electrochemical corrosion: This occurs when stainless steel surfaces contain metal dust or other metal particles that, in humid air, form a micro-battery with the condensed water, damaging the protective film.
  • Corrosion by organic acids: This happens when stainless steel surfaces are contaminated with organic juices (such as from melons or noodle soup), which form organic acids in the presence of water and oxygen and eventually corrode the metal surface.
  • Local corrosion: This occurs when stainless steel surfaces are contaminated with acid, alkali, or salt substances (such as from alkaline water or lime water spray), leading to localized corrosion.
  • Chemical corrosion: This happens in polluted air (with high levels of sulfur, oxides, and oxidized oxygen) when sulfuric acid, nitric acid, and acetic acid form in condensed water and cause chemical corrosion.

How to prevent stainless steel from rusting?

The conditions mentioned above can damage and corrode the protective film on the stainless steel surface.

To maintain a bright, rust-free metal surface, we recommend:

  • Regular cleaning and scrubbing of the stainless steel surface to remove contaminants and prevent external factors from causing rust.
  • Using 201 or 202 stainless steel in non-industrial and non-corrosive environments, as these types are more prone to rusting in coastal areas.
  • Using 304-grade stainless steel in coastal areas, as it is resistant to seawater corrosion.

How To Deal With Stainless Steel Rust?

a) Chemical Methods:

Using pickling paste or spray to help remove rust and reform a chromium oxide film can restore the stainless steel’s corrosion resistance.

It is crucial to properly wash the stainless steel with water after pickling to remove any contaminants and acid residue.

Stainless steel pickling pastes

After all processes, use polishing equipment to repolish the stainless steel and seal it with polishing wax.

For small, mild rust stains, a mixture of 1:1 gasoline and engine oil can also be used to remove them.

b) Mechanical Methods:

Sandblast cleaning, cleaning with glass or ceramic particles, grinding, cleaning and polishing.

Stainless Steel Sandblast Cleaning

It is possible to erase previously applied materials, polishing materials, or cover polluted areas through mechanical means.

However, all forms of pollution, especially exotic iron particles, can be a source of corrosion, especially in humid environments.

Thus, it is best to clean the surface of the metal through mechanical means when it is dry.

Please note that mechanical cleaning can only clean the surface of the metal, not change its anti-corrosion ability.

We recommend using polishing equipment to repolish the surface after mechanical cleaning and sealing it with polishing wax.

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Shane
Author

Shane

Founder of MachineMFG

As the founder of MachineMFG, I have dedicated over a decade of my career to the metalworking industry. My extensive experience has allowed me to become an expert in the fields of sheet metal fabrication, machining, mechanical engineering, and machine tools for metals. I am constantly thinking, reading, and writing about these subjects, constantly striving to stay at the forefront of my field. Let my knowledge and expertise be an asset to your business.

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