Alloy Steels: Definition, Types, Applications & More!

1. Classification of Alloy Steels Alloy steels are essentially carbon steels enhanced with additional alloying elements such as Si, Mn, W, V, Ti, Cr, Ni, Mo, etc. These elements improve various properties of the steel like strength, toughness, hardenability, and weldability. Alloy steels are often categorized based on the content of alloying elements. Furthermore, alloy […]

Alloy Steels Definition, Types, Applications & More!

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1. Classification of Alloy Steels

Alloy steels are essentially carbon steels enhanced with additional alloying elements such as Si, Mn, W, V, Ti, Cr, Ni, Mo, etc.

These elements improve various properties of the steel like strength, toughness, hardenability, and weldability. Alloy steels are often categorized based on the content of alloying elements.

Furthermore, alloy steels are employed specifically across different industries, and thus, they are commonly classified according to their application as well.

Classification by Alloy Content

  • Low-alloy steel: Total alloy content less than 5%
  • Medium-alloy steel: Total alloy content between 5% to 10%
  • High-alloy steel: Total alloy content above 10%

Classification by Usage

  • Alloy Structural Steel: Ordinary low-alloy steel; alloy carburizing steel, alloy quenched and tempered steel, alloy spring steel; ball bearing steel.
  • Alloy Tool Steel: Alloy cutting steel (including low-alloy cutting steel, high-speed steel); alloy mold steel (including cold-work mold steel, hot-work mold steel); gauge steel.
  • Special Performance Steel: Stainless steel, heat-resistant steel, abrasion-resistant steel, etc.

2. Alloy Steel Numbering

1) Low Alloy High Strength Structural Steel

Its grade is arranged in the sequence of Chinese Pinyin letter (Q) representing yield point, yield limit value, and quality grade symbol (A, B, C, D, E).

For example, Q390A signifies low alloy high strength structural steel with yield strength σs = 390N/mm2, quality grade A.

2) Alloy Structural Steel

Its grade is formed by “two digits + element symbol + digit”.

The first two digits represent the ten thousandths of the average carbon content by mass in the steel, the element symbol indicates the alloying elements contained in the steel, and the number after the element symbol represents the hundredths of the average content of that element by mass.

If the average mass fraction of the alloy element is less than 1.5%, only the element is marked without a value. When the average mass fraction is ≥1.5%, ≥2.5%, ≥3.5%, etc., the numbers 2, 3, 4, etc., are marked after the alloy element accordingly.

For example, 40Cr, where the average mass fraction of carbon Wc=0.4%, and the average mass fraction of chromium WCr <1.5%. If it is high-grade quality steel, “A” is added at the end of the grade, such as 38CrMoAlA steel, which is a high-grade quality alloy structural steel.

3) Rolling Bearing Steel

The letter “G” (the first letter of the Chinese Pinyin of the word “rolling”) is added before the grade, and the number after indicates the thousandths of the chromium content by mass, while the carbon content is not indicated.

For example, GCr15 steel is rolling bearing steel with an average mass fraction of chromium WCr = 1.5%.

If other alloying elements are present in chromium bearing steel, they are expressed in the same way as general alloy structural steel. All rolling bearing steels are high-grade quality steels, but the grade does not end with “A”.

4) Alloy Tool Steel

The numbering method of this type of steel is similar to that of alloy structural steel, except that when Wc < 1%, a single digit is used to represent the thousandths of the carbon content by mass. When the carbon mass fraction is ≥1%, it is not indicated.

For example, in Cr12MoV steel, the average mass fraction of carbon is Wc=1.45%~1.70%, so it is not indicated; the average mass fraction of Cr is 12%, and the mass fractions of Mo and V are both less than 1.5%.

However, high-speed tool steels are exceptions, and the average mass fraction of carbon is not indicated regardless of the amount. Since both alloy tool steels and high-speed tool steels are high-grade quality steels, there is no need to mark “A” at the end of their grade.

5) Stainless Steel and Heat-resistant Steel

The number in front of the steel grade indicates the thousandths of the carbon mass fraction.

For example, in 3Cr13 steel, the average mass fraction Wc=0.3%, and the average mass fraction WCr=13%. When the carbon mass fraction Wc≤0.03% and Wc≤0.08%, the prefixes “00” and “0” are used respectively, for example, 00Cr17Ni14Mo2, 0Cr19Ni9 steels, etc.

3. Explanation of Common Alloy Steels

1) Ordinary Low Alloy Steel

Q345

Applications: Mainly used for making bridges, ships, vehicles, boilers, pressure vessels, oil and gas pipelines, large steel structures, etc. It is used in the hot-rolled air-cooled state, the structure is fine-grained F+P, and it is not heat-treated anymore.

Chemical composition wt%
CMnSiVNbTi
0.18~0.201.0~1.60.550.02~0.150.015-0.060.02~0.2

The Q345 includes old steel grades 12MnV, 14MnNb, 16Mn, 18Nb, 16MnCu.

Thickness mmMechanical properties
σs MPaσb MPaσ5 %Akv (20 ℃) J
<16≥ 345470-63021-2234
16-35≥ 325
35-50≥ 295

Q420

Used in the normalized state, the structure is F+S. Q345 includes old steel grades 15MnVN, 14MnVTiRE.

Chemical composition wt%
CMnSiVNbTiCrNi
≤ 0.201.0~1.70.550.02~0.20.015-0.060.02~0.2≤ 0.40≤ 0.70
Thickness mmMechanical properties
σs MPaσb MPaσ5 %Akv (20 ℃) J
<16≥ 420520-68018-19
GB/T159
3491-1994
16-35≥ 400
35-50≥ 380

2) Alloy Quenched and Tempered Steel (Low Hardenability)

40Cr

Applications: Used to manufacture various important parts on automobiles, tractors, machine tools, and other machines, such as gears of machine tools, main shafts, automobile engine crankshafts, connecting rods, bolts, intake valves.

Main chemical composition wt%C0.37-0.44
Mn0.5-0.8
Si0.17-0.37
Cr0.81-1.1
Mo0.07-0.12
Heat treated blank size<25mmQuenching ℃850 oil
Tempering ℃520 water oil
Mechanical properties (≥)σb MPa980
σs MPa785
Heat-treated blank size<25mm9
ψ %45
Akv J47
Annealed HB207

3) Alloy Spring Steel

65Mn 60Mn2Si

Examples of applications of 65Mn 60Mn2Si steel: springs with a section ≤25mm, such as vehicle buffer coil springs.

Steel grade65Mn60Si2Mn
Main components w%C0.62-0.700.56-0.64
Mn0.90-1.200.60-0.90
Si0.17-0.371.50-2.00
Cr≤ 0.25≤ 0.35
Heat treatmentQuenching ℃830 oil870 oil
Tempering540480
Mechanical propertiesσs MPa8001200
σb MPa10001300
δ10 %85
ψ %3025

20Cr

Applications: Can manufacture gears in automobiles, tractors, camshafts on internal combustion engines, piston pins, and other machine parts. It can withstand strong frictional wear, larger alternating loads, especially impact loads.

Main chemical composition wt%C0.17-0.24
Mn0.5-0.8
Si0.20-0.40
Cr0.7-1.0
Heat treatment ℃Carbon930
Preparation processing880 water&oil
Quenching780-820 water&oil
Tempering200
Mechanical properties (≥)σb MPa835
σs MPa540
δ5 %10
ψ %4o
Akv J47
Blank size mm<15

4) Alloy Carburizing Steel (Medium Hardenability):

20CrMnTi

Main chemical composition wt%C0.17-0.24
Mn0.8-1.10
Si0.17-0.37
Cr1.0-1.3
Heat treatment ℃Carbon930
Preparation processing880 water&oil
Quenching770 water&oil
Tempering200
Mechanical properties (≥)σb MPa1080
σs MPa850
δ5 %10
ψ %45
Akv J55
Blank size mm<15

5) Roller Bearing Steel:

GCr15:

Used to manufacture the rolling elements (balls, rollers, needles) of rolling bearings, inner and outer rings, etc. It can also be used to make precision gauges, cold punch dies, machine tool lead screws, and other wear-resistant parts.

Main chemical composition wt%C0.95-1.05
Cr1.40~1.65
Si0.15~0.35
Mn0.25~0.45
Heat treatment specification performanceQuenching ℃820~ 840
Tempering ℃150~160
HRC after tempering62~66
Main purposeFerrules with a wall thickness of<14mm and an outer diameter of 250mm. A steel ball with a diameter of 25-200mm. A roller with a diameter of approximately 25mm.

6) Low Alloy Cutting Tool Steel:

9SiCr, CrWMn

Steel grade9SiCrCrWMn
Chemical composition wt%C0.85-0.950.9-1.05
Mn0.3-0.60.8-1.1
Si1.2-1.60.15-0.35
Cr0.95-1.250.9-1.2
W1.2-1.5
Heat treatmentOil quenchingQuenching temperature ℃≥62
Hardness HRC180-200140-160
TemperingTempering temperature ℃60-6262-65
Hardness HRCDie, tap, drill bit, reamer, gear milling cutter, cold stamping die, cold rolling rollerDies, broaches, gauges, complex and high-precision stamping dies, etc

7) High-Speed Steel:

W18Cr4V

CMnSiCrWVManufacturing high-speed cutting tools, planers, drills, milling cutters, etc
0.7~0.80.1~0.40.2~0.43.8~4.417.5-19.01.0~1.4

8) Cold Mold Steel:

Cr12:

Used to make various cold punch molds, cold heading molds, cold extrusion molds, and wire drawing molds, etc. For large cold molds made of Cr12 steel, there is minimal heat treatment deformation, making it suitable for manufacturing heavy-duty and complex molds.

Chemical composition wt%
CSiMnCrV
2.00-2.30≤ 0.40≤ 0.4011.50-13.500.15~0.30
AnnealingOil quenchingTempering
Temperature ℃Hardness HBTemperature ℃Temperature ℃Hardness HRC
870-900207-255950-1000200-45058-64

Usage Example: Cold Stamping Die, Drawing Die, Stamping Die, Rolling Die

9) Hot Mold Steel:

4Cr5MoSiV:

Its structure consists of tempered martensite, granular carbides, and a small amount of residual austenite. To ensure hot hardness, it is necessary to perform multiple tempering.

Chemical composition wt%
CSiMnCrMoV
0.32-0.420.80-1.200.404.50-5.501.00-1.500.30-0.50
AnnealingOil quenchingTempering
Temperature ℃Hardness HBTemperature ℃Temperature ℃Hardness HRC
840-900209-2291000-1025540-65040-54

Examples of uses: hot heading die, die-casting die, hot extrusion die, precision forging die

10) Gauge Steel

Measuring toolSteel grade
Flat template or card board10. 20 or 50, 55, 60, 60Mn, 65Mn
General gauges and block gaugesT10A, T12A, 9SiCr
High precision gauges and block gaugesCr (cutting tool steel), CrMn, GCr15
High precision and complex shaped gauges and block gaugesCrWMn (low deformation steel)
Corrosion resistant measuring tool4Cr13,9Cr18 (stainless steel)

11) Stainless Steel:

Stainless steel refers to steel types with high corrosion resistance in the atmosphere and general media.

Steel GradeChemical composition wt%σbσ0.2δ5ψAkHardness
CCrMPaMPa%%J
1Cr13
M Type
≤0.1511.5-13.5≥540≥345≥25≥55≥78≥159 HB
Heat treatment: 9501000 ℃ oil or water quenching, 700750 ℃ rapid cooling and tempering;
Purpose: To produce parts that are resistant to weakly corrosive media and can withstand impact loads, such as steam turbine blades, water pressure machine valves, structural frames, bolts, nuts, etc
9Cr18
M Type
0.9-1.017-19≥55 HRC
Heat treatment: 1000-1050 ℃ oil quenching, 200-300 ℃ oil, air cooling and tempering;
Usage: stainless slicing mechanical cutting tool, cutting tool, surgical blade, high abrasion resistant and corrosion resistant part
1Cr17
F Type
≤0.1216-18≥450≥205≥22≥50≥183 HB
Heat treatment 780 ° C~850 ° C air cooling.
Purpose: To produce nitric acid factory equipment, such as absorption towers, heat exchangers, acid tanks, conveying pipelines, and food factory equipment

Martensitic Stainless Steel:

1Cr13, 2Cr13, 3Cr13, 4Cr13, etc. They all have sufficient corrosion resistance in oxidative media. Low carbon 1Cr13 and 2Cr13 steel have better corrosion resistance and good mechanical properties. As the carbon content increases, 3Cr13 and 4Cr13 steel have increased strength and wear resistance, but reduced corrosion resistance.

Ferritic Stainless Steel:

1Cr17, 1Cr17Ti, etc. This type of steel has a chromium mass fraction of 17%~30% and a carbon mass fraction lower than 0.15%. It has a single-phase ferrite structure and better corrosion resistance than Cr13 steel.

Austenitic Stainless Steel:

Cr18Ni9 type (also known as 18-8 type stainless steel) is one of the most commonly used stainless steels. This type of austenitic stainless steel has a low carbon content (around 0.1%) and excellent corrosion resistance. The steel often includes additions of Ti (Titanium) or Nb (Niobium) to prevent intergranular corrosion.

This class of steel has lower strength and hardness, and it’s non-magnetic. However, it offers superior plasticity, toughness, and corrosion resistance compared to Cr13 type stainless steel. A solution treatment can further improve the corrosion resistance of this austenitic stainless steel.

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Shane
Author

Shane

Founder of MachineMFG

As the founder of MachineMFG, I have dedicated over a decade of my career to the metalworking industry. My extensive experience has allowed me to become an expert in the fields of sheet metal fabrication, machining, mechanical engineering, and machine tools for metals. I am constantly thinking, reading, and writing about these subjects, constantly striving to stay at the forefront of my field. Let my knowledge and expertise be an asset to your business.

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